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A growing body of evidence has demonstrated that kynurenine pathway activity is generally increased in COPD and its acute exacerbations: the KYN/TRP ratio has been found to be elevated in peripheral blood or respiratory samples in several studies and is associated with inflammatory markers, suggesting a potential role of this pathway in the inflammation-metabolism crosstalk in COPD

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Ascorbic acid is believed to form a charge couple with GSH which enhances penetration through cell membranes, and reduces the tendency for the gamma-glutamyl and glycinyl residues to assume a cyclic conformation or to form an internal cyclic amide

I cover more on this phenomenon in my folate article

Modification of PET track-etched membranes for membrane distillation of low-level liquid radioactive waste and salt solutions