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Mechanism of cytotoxicity of anticancer platinum drugs: evidence that cis-diamminedichloroplatinum(II) and cis-diammine-(1,1-cyclobutanedicarboxylato)platinum(II) differ only in the kinetics of their interaction with DNA

Tyrosol (E) (-5.9 kcal/mol) only forms a single hydrogen bond with SER283, while its solvent-exposed position and lack of interaction in the image explain the high RMSD value (~ 3.5 )

And previous studies in our laboratory have shown that conversion of Cys residues into Sec residues in GPx1 and GPx4 could result in dramatic loss of the catalytic activity 15,16

This leads to the inability to absorb B12 and thus deficiency

At the clinical strategy level, the establishment of quantifiable metabolic readouts, such as the Kyn/Trp ratio, the expression of key metabolic enzymes or transporters, and the proportions of signaling metabolites, combined with stratified interventions based on disease stage and tissue involvement, may help further promote tissue repair and restoration of immune homeostasis while suppressing inflammatory responses, thereby enabling treatment strategies for autoimmune diseases with greater long-term benefit (139)

Consistent with previous studies in mice, we also observed an increase in branched-chain amino acids (Leucine, Isoleucine, and Valine) in the brains of both DL and CR-fed female mice 12,83