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doi: 10.1038/s41385-019-0162-4 128 BaumeisterTProao-VascoAMetwalyAKleigreweKKuznetsovASchmigLet al

Free Radic Biol Med 95:2742 Creissen G, Firmin J, Fryer M, Kular B, Leyland N, Reynolds H, Pastori G, Wellburn F, Baker N, Wellburn A, Mullineaux P (1999) Elevated glutathione biosynthetic capacity in the chloroplasts of transgenic tobacco plants paradoxically causes increased oxidative stress

the excess free radicals deplete glutathione reserves, and the decreased ATP production slows glutathione replenishment, ultimately resulting in chronic glutathione deficiency [8]

Inhibition of NF-kappa B binding to DNA by chromium, cadmium, mercury, zinc, and arsenite in vitro : evidence of a thiol mechanism Arch Biochem Biophys 1998 349 : 356362 Yang JP, Merin JP, Nakano T, Kato T, Kitade Y, Okamoto T

This is where the concept of bioavailability comes in