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HHQs are most commonly synthesized through multicomponent reactions, with Hantzsch-type condensations remaining the dominant synthetic route due to their operational simplicity, and ability to rapidly generate molecular diversity ( More recently, significant efforts have focused on improving the efficiency, sustainability, and scope of HHQ synthesis

1 Introduction Bullfrog belongs to Amphibia, Frog family, native to North America, is an aquaculture animal with high efficiency in producing high quality protein, which was introduced to our country from Cuba in the 1960s

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Most solid tumors are plugged into the systemic circulation through the stroma , a mixture of non-malignant cells pertinent -but not limited- to the hosting tissue such as fibroblasts, nerve and immune cells, blood vessels, extracellular matrix proteins and adipocytes 20 , representing up to 90% of tumor mass 21

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TRX and other thiol compounds exert a protective activity against cytotoxicity and apoptosis induced by various oxidative stresses